Database of Zeolite Structures
 
Framework Type ZON
31P MAS NMR spectrum of calcined AlPO-ZON


Note: Toggle plots by clicking on the legend

Peak
T site
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Assigment
(topological)
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
P2
T1
Q4(4Al)
-33.05
1.000
2.33
0.226
P4
T4
Q4(4Al)
-29.33
1.000
1.64
0.226
P1/P3
T2/T3
Q4(4Al)
-24.94
1.000
1.44
0.226
P3/P1
T3/T2
Q4(4Al)
-24.26
1.000
1.44
0.226


References
Spectrum

  Authors: Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
  Title: Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
  Reference: Microporous Mesoporous Mater., 63, 163-176 (2003)
  Figure: Figure 4b  

Peak Assignment

  Authors: Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
  Title: Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
  Reference: Microporous Mesoporous Mater., 63, 163-176 (2003)
  Method: 2D correlation NMR
  Figure: Figure 4b  

Crystal Structure

  Authors: Roux, M., Marichal, C., Le Meins, J.M., Baerlocher, C., Chezeau, J.M.
  Title: Solid state NMR and X-ray diffraction study of three forms of the aluminophosphate AlPO4-ZON
  Reference: Microporous Mesoporous Mater., 63, 163-176 (2003)

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
Spectrum information

  Obs. freq. 161.9 MHz (Field = 9.4 Tesla)
  Pulse sequence single pulse
  MAS frequency 3.5-8 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentPeak assignments are based on a 2D 31P/31P correlation spectrum

Chemical Formula

  [Al - P - O]-ZON

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)

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