Database of Zeolite Structures
 

Framework Type HZF
Reference Material
  Material Name: ZEO-5    
 
Chemical Formula:
 
[Si96O192]-HZF
   
Unit Cell:
 
monoclinic

 C 1 2/c 1 (# 15)
    a' = 25.2780 Å b' = 24.6650 Å c' = 14.4173 Å  
    α' = 90.000° β' = 105.244° γ' = 90.000°  
   
Framework Density:
 
11.1 T/1000 Å3
 
 
Channels:
 
[[001] 20 10.7 x 10.7* <-> <110> 16 8.0 x 11.5**]***
Dimensionality
  Sorption (molecular cross section > 3.4Å): 3-dimensional
  Topological (pore opening > 6-ring): 3-dimensional
   
References:
  Gao, Z.R., Yu, H., Chen, F.-J., Mayoral, A., Niu, Z., Niu, Z., Li, X., Deng, H., Márquez-Álvarez, C., He, H., Xu, S., Zhou, Y., Xu, J., Xu, H., Fan, W., Balestra, S.R.G., Ma, C., Hao, J., Li, J., Wu, P., Yu, J. and Camblor, M.A.
  "Interchain-expanded extra-large-pore zeolites"
Nature, 628, 99-103 (2024)
 
 
Name and Code derivation:
    Nanostructured Hybrid, Biohybrid and Porous Materials Group - ZEO-five
  Hybrid ZEO-5 (five)
  HZF
Limiting Rings
 
20-ring viewed along [001]

16-ring viewed along [110]