Database of Zeolite Structures
 

Framework Type BOZ
Reference Material
  Material Name: Be-10    
 
Chemical Formula:
 
|(EA, H2O)x| [Be66.7As25.3O80.5(OH)103.5]-BOZ  [1]

EA = C2H7N = ethylamine = ethanamine
SMILES: CCN   Images:  stick or 3D
   
Unit Cell:
 
monoclinic

 P 1 21/m 1 (# 11)
    a' = 13.9570 Å b' = 14.1940 Å c' = 34.9230 Å  
    α' = 90.000° β' = 89.970° γ' = 90.000°  
   
Framework Density:
 
13.3 T/1000 Å3
 
 
Channels:
 
[100] 10 5.3 x 6.4* <-> [010] 10 3.3 x 6.0* <-> [001] 8 2.5 x 3.6*
Dimensionality
  Sorption (molecular cross section > 3.4Å): 1-dimensional
  Topological (pore opening > 6-ring): 3-dimensional
 
Stability:
 
framework starts to lose structural integrity when heated above 250˚C
   
References:
  Littlefield, B.T.R. and Weller, M.T.
  "Lightweight nanoporous metal hydroxide-rich zeotypes"
Nature Commun., 3, art. no. 1114 (2012)
 
 
Name and Code derivation:
    Be-10 one-zero)
  BOZ
 
 
  1 Protons (OH-groups) assumed to be on the framework O's to balance the charge
Limiting Rings
 
10-ring viewed along [100]

10-ring viewed along [010]

8-ring viewed along [001]